| # | Team | Player | Pos | High School/College |
| 1 | Houston | Carlos Correa | SS | Puerto Rico Baseball Academy |
| 2 | Minnesota | Byron Buxton | OF | Appling County HS, GA |
| 3 | Seattle | Mike Zunino | C | Florida |
| 4 | Baltimore | Kevin Gausman | RHP | LSU |
| 5 | Kansas City | Kyle Zimmer | RHP | San Francisco |
| 6 | Chicago Cubs | Albert Almora | OF | Mater Academy, FL |
| 7 | San Diego | Max Fried | LHP | Harvard-Westlake HS, CA |
| 8 | Pittsburgh | Mark Appel | RHP | Stanford |
| 9 | Miami | Andrew Heaney | LHP | Oklahoma State |
| 10 | Colorado | David Dahl | OF | Oak Mountain HS, AL |
| 11 | Oakland | Addison Russell | SS | Pace HS, FL |
| 12 | NY Mets | Gavin Cecchini | SS | Barbe HS, LA |
| 13 | Chicago W/Sox | Courtney Hawkins | OF | Carroll HS, TX |
| 14 | Cincinnati | Nick Travieso | RHP | Archbishop McCarthy HS, FL |
| 15 | Cleveland | Tyler Naquin | OF | Texas A&M |
| 16 | Washington | Lucas Giolito | RHP | Harvard-Westlake HS, CA |
| 17 | Toronto | D.J. Davis | OF | Stone HS, MS |
| 18 | Los Angeles | Corey Seager | SS | Northwest Cabarrus HS, NC |
| 19 | St. Louis | Michael Wacha | RHP | Texas A&M |
| (Compensation for Albert Pujols - Type A) |
| 20 | San Francisco | Chris Stratton | RHP | Mississippi State |
| 21 | Atlanta | Lucas Sims | RHP | Brookwood HS, GA |
| 22 | Toronto | Marcus Stroman | RHP | Duke |
| (Compensation for 2011 unsigned draft pick) |
| 23 | St. Louis | James Ramsey | OF | Florida State |
| 24 | Boston | Deven Marrero | SS | Arizona State |
| 25 | Tampa Bay | Richie Shaffer | 3B | Clemson |
| 26 | Arizona | Stryker Trahan | C | Acadiana HS, LA |
| 27 | Milwaukee | Clint Coulter | C | Union HS, WA |
| (Compensation for Prince Fielder - Type A) |
| 28 | Milwaukee | Victor Roache | OF | Georgia Southern |
| 29 | Texas | Lewis Brinson | OF | Coral Springs HS, FL |
| 30 | NY Yankees | Ty Hensley | RHP | Santa Fe HS, OK |
| 31 | Boston | Brian Johnson | LHP | Florida |
| (Compensation for Jonathan Papelbon - Type A) |
| COMPENSATION ROUND | A | | |
| 32 | Minnesota | Jose Berrios | RHP | Papa Juan XIII HS, PR |
| (Compensation for Michael Cuddyer - Type A) |
| 33 | San Diego | Zach Eflin | RHP | Hagerty HS, FL |
| (Compensation for Heath Bell - Type A) |
| 34 | Oakland | Daniel Robertson | SS | Upland HS, CA |
| (Compensation for Josh Willingham - Type A) |
| 35 | NY Mets | Kevin Plawecki | C | Purdue |
| (Compensation for Jose Reyes - Type A) |
| 36 | St. Louis | Stephen Piscotty | 3B | Stanford |
| (Compensation for Albert Pujols - Type A) |
| 37 | Boston | Pat Light | RHP | Monmouth |
| (Compensation for Jonathan Papelbon - Type A) |
| 38 | Milwaukee | Mitch Haniger | OF | Cal Poly |
| (Compensation for Prince Fielder - Type A) |
| 39 | Texas | Joey Gallo | 3B | Bishop Gorman HS, NV |
| (Compensation for C.J. Wilson - Type A) |
| 40 | Philadelphia | Shane Watson | RHP | Lakewood HS, CA |
| (Compensation for Ryan Madson - Type A) |
| 41 | Houston | Lance McCullers | RHP | Jesuit HS, FL |
| (Compensation for Clint Barmes - Type B) |
| 42 | Minnesota | Luke Bard | RHP | Georgia Tech |
| (Compensation for Jason Kubel - Type B) |
| 43 | Chicago Cubs | Pierce Johnson | RHP | Missouri State |
| (Compensation for Aramis Ramirez - Type B) |
| 44 | San Diego | Travis Jankowski | OF | SUNY Stony Brook |
| (Compensation for Aaron Harang - Type B) |
| 45 | Pittsburgh | Barrett Barnes | OF | Texas Tech |
| (Compensation for Ryan Doumit - Type B) |
| 46 | Colorado | Eddie Butler | RHP | Radford |
| (Compensation for Mark Ellis - Type B) |
| 47 | Oakland | Matt Olson | 1B | Parkview HS, GA |
| (Compensation for David DeJesus - Type B) |
| 48 | Colorado | Keon Barnum | 1B | King HS, FL |
| (Compensation for Mark Buehrle - Type B) |
| 49 | Cincinnati | Jesse Winker | OF | Olympia HS, FL |
| (Compensation for Ramon Hernandez - Type B) |
| 50 | Toronto | Matt Smoral | LHP | Solon HS, OH |
| (Compensation for Frank Francisco - Type B) |
| 51 | Los Angeles | Jesmuel Valentin | SS | Puerto Rico Baseball Academy |
| (Compensation for Rod Barajas - Type B) |
| 52 | St. Louis | Patrick Wisdom | 3B | St. Mary's |
| (Compensation for Octavio Dotel - Type B) |
| 53 | Texas | Colin Wiles | RHP | Blue Valley West HS, KS |
| (Compensation for Darren Oliver - Type B) |
| 54 | Philadelphia | Mitch Gueller | RHP | WF West HS, WA |
| (Compensation for Raul Ibanez - Type B) |
| 55 | San Diego | Walker Weickel | RHP | Olympia HS, FL |
| (Compensation for 2011 unsigned draft pick) |
| 56 | Chicago Cubs | Paul Blackburn | RHP | Heritage HS, CA |
| (Compensation for Carlos Pena - Type B) |
| 57 | Cincinnati | Jeff Gelalich | OF | UCLA |
| (Compensation for Francisco Cordero - Type B) |
| 58 | Toronto | Mitch Nay | 3B | Hamilton HS, AZ |
| (Compensation for Jon Rauch - Type B) |
| 59 | St. Louis | Steve Bean | C | Rockwall HS, TX |
| (Compensation for Edwin Jackson - Type B) |
| 60 | Toronto | Tyler Gonzalez | RHP | James Madison HS, TX |
| (Compensation for Jose Molina - Type B) |
| | | | |
| 14:11:45 ET | | | |
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